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Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm3). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS 187Os/189Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM 187Os/189Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.  相似文献   
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The physical and chemical properties of aerosol particles were investigated at Plan d'Aups, one of the ESCOMPTE sites located in the St. Baume mountain area (700 m a.s.l.), 50 km east of Marseilles (France). The site is ideally located for assessing the vertical and horizontal extent of the pollution plume from the Marseilles–Berre area.Our study showed that polluted air masses from the Marseilles–Berre area are advected to Plan d'Aups in the early afternoon. Average daily concentration of particles reaches up to 40 μg m−3 while 1-h average particle number concentration is greater than 30,000 cm−3. Most of the particle mass is composed of SO42− and organic carbon (OC). The chemical properties of the particles revealed that an additional source, possibly from the industrial area of Gardanne, contributes to the aerosol mass. This last source is characterised by significant emissions of elements, such as Zn, V, Al and Si.In addition to transport, we found that gas-to-particle conversion takes place at the interface between the free troposphere and the boundary layer. We estimated that on average, 30% of the particle number is accounted for by direct nucleation. This is potentially a major aerosol source to the free troposphere.  相似文献   
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We present here the numerical application of the theoretical results derived in Correia et al. (2003, Icarus 163, 1-23) for the spin evolution of Venus since its formation. We explore a large variety of initial conditions to cover the possible formation and evolutionary scenarios. In particular, we pay special attention to the evolutions which cross the chaotic zone resulting from secular planetary perturbations (Laskar and Robutel, 1993, Nature 361, 608-612). We demonstrate that Venus’ axis can be temporarily trapped in a secular resonance with the node of Neptune’s orbit, which can prevent it from being tilted to 180° and will drive it toward 0°. We test several dissipation models and parameters to evaluate their contribution to the planet’s spin history. We confirm that despite the variations in the models, only three of the four final spin states of Venus are possible (Correia and Laskar, 2001, Nature 411, 767-770) and that the present observed retrograde spin state of Venus can be attained by two different processes. In the first scenario (π−), the axis is tilted toward 180° while its rotation rate slows down, while in the second one, the axis is driven toward 0° obliquity and the rotation rate decreases, stops, and increases again in the reverse direction to a final equilibrium value (0−).  相似文献   
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A numerical model based on smoothed particle hydrodynamics (SPH) was developed and used to simulate immiscible and miscible fluid flows in porous media and to study effects of pore scale heterogeneity and anisotropy on such flows.  相似文献   
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The load of pathogenic bacteria, their fate and their dangerousness in the Tietê River were assessed along 100 km starting from the city of São Paulo, Brazil. The data were compared with those from two German rivers. High loads of pathogens were found in the Tietê River near the city of São Paulo (Escherichia coli O157:H7, Shigella flexneri, and Shigella boydii), which were absent 30 km downstream of São Paulo. The antibiotic resistances observed in the Tietê river were rather low and decreased after the major input in São Paulo to significantly lower levels about 30 km downstream. While the Brazilian isolates were more susceptible for ampicillin than the German ones, the reverse was observed for gentamycin. For optimal control of infections in humans critical areas where these bacteria survived longer and their elimination mechanisms should be identified as well as the extent and the origin of antibiotic resistance should be determined.  相似文献   
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In the framework of the planar and circular restricted three-body problem, we consider an asteroid that orbits the Sun in quasi-satellite motion with a planet. A quasi-satellite trajectory is a heliocentric orbit in co-orbital resonance with the planet, characterized by a nonzero eccentricity and a resonant angle that librates around zero. Likewise, in the rotating frame with the planet, it describes the same trajectory as the one of a retrograde satellite even though the planet acts as a perturbator. In the last few years, the discoveries of asteroids in this type of motion made the term “quasi-satellite” more and more present in the literature. However, some authors rather use the term “retrograde satellite” when referring to this kind of motion in the studies of the restricted problem in the rotating frame. In this paper, we intend to clarify the terminology to use, in order to bridge the gap between the perturbative co-orbital point of view and the more general approach in the rotating frame. Through a numerical exploration of the co-orbital phase space, we describe the quasi-satellite domain and highlight that it is not reachable by low eccentricities by averaging process. We will show that the quasi-satellite domain is effectively included in the domain of the retrograde satellites and neatly defined in terms of frequencies. Eventually, we highlight a remarkable high eccentric quasi-satellite orbit corresponding to a frozen ellipse in the heliocentric frame. We extend this result to the eccentric case (planet on an eccentric motion) and show that two families of frozen ellipses originate from this remarkable orbit.  相似文献   
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Species richness is a measure that is fundamental to many studies in ecology, and it is particularly important on sandy beaches, where it underlies patterns described by the broadly accepted swash exclusion hypothesis. However, its estimation in practice is problematic. This has led ecologists in other fields to adopt extrapolative estimators of species richness, which project the total number of species present in a habitat by adjusting upward the number of species observed by an amount related to the number of rare species encountered in the samples. In so doing, the species richness can be estimated, with confidence intervals, at any level of sampling effort. Despite the availability and advantages of these methods, beach ecologists have continued to use the observed species richness as a point estimate of biodiversity for beaches. Here, we employ a Monte Carlo resampling approach over a range of routine transect designs used to sample sandy beaches, and evaluate the performance of seven non-parametric extrapolative estimators for species richness relative to that of the more conventionally used observed species richness. We find that the first-order Jackknife estimator (Jack 1) is the least biased, most accurate and most consistent across sites. Employing this estimator would allow accurate estimation of species richness on short (tens of metres) stretches of beach without exceeding the acceptable levels of sampling effort (4–5 m2). Spreading this effort evenly over three across-shore transects, each with a minimum of 13 equally spaced levels seems appropriately efficient. Although a greater number of research studies is required to ascertain the generality of these results beyond the beaches we sampled, we tentatively recommend the application of our results in biodiversity surveys on sandy beaches.  相似文献   
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